Staling is a chemical and physical process in bread that reduces its palatability. Stale bread is dry and leathery.
Staling is not, as is commonly believed, simply a drying out process. Bread will stale even in a moist environment, and stales most rapidly at temperatures just above freezing.[1]
Although the precise mechanism of staling is still unknown, one important mechanism appears to be migration of moisture from the starch granules into the interstitial spaces, degelatinizing the starch. This results in stale bread's leathery texture.