NotationIf An alternative notation involves placing the operator inside two colons denoted by BosonsBosons satisfy Bose-Einstein statistics. Single bosonsIf we start with only one type of boson there are two operators of interest:
These satisfy the commutator relationship where Examples1. We'll consider the simplest case first. This is the normal ordering of The expression 2. A more interesting example is the normal ordering of Here the normal ordering operation has reordered the terms by placing These two results can be combined with the commutation relation obeyed by or This equation is used in defining the contractions used in Wick's theorem. 3. An example with multiple operators is: 4. A more complicated example shows how we can normal order functions of operators by expanding them out in a series and normal ordering each term: Multiple bosonsIf we now consider N different bosons there are 2N operators:
Here These satisfy the commutation relations: where These may be rewritten as: Examples1. For two different bosons (N = 2) we have 2. For three different bosons (N = 3) we have Notice that since (by the commutation relations) FermionsFermions satisfy Fermi-Dirac statistics. Single fermionsFor a single fermion there are two operators of interest:
These satisfy the anticommutator relationships where To define the normal ordering of an product of fermionic creation and annihilation operators we must take into account the number of interchanges between neighbouring operators. We get a minus sign for each such interchange. Examples1. We again start with the simplest cases: This expression is already in normal order so nothing is changed. Here we introduce a minus sign because we have changed the order of two operators. These can be combined, along with the anticommutation relations, to show or This equation, which is in the same form as the bosonic case above, is used in defining the contractions used in Wick's theorem. 2. The normal order of any more complicated cases gives zero because there will be at least one creation or annihilation operator appearing twice. For example: Multiple fermionsFor N different fermions there are 2N operators:
Here These satisfy the commutation relations: where These may be rewritten as: When calculating the normal order of products of fermion operators we must take into account the number of interchanges of neighbouring operators required to rearrange the expression. It is as if we pretend the creation and annihilation operators anticommute and then we reorder the expression to ensure the creation operators are on the left and the annihilation operators are on the right - all the time taking account of the anticommutation relations. Examples1. For two different fermions (N = 2) we have Here the expression is already normal ordered so nothing changes. Here we introduce a minus sign because we have interchanged the order of two operators. Note that the order in which we write the operators here, unlike in the bosonic case, does matter. 2. For three different fermions (N = 3) we have Notice that since (by the anticommutation relations) Similarly we have Uses in quantum field theoryThe vacuum expectation value of a normal ordered product of creation and annihilation operators is zero. This is because, denoting the vacuum state by (here Any normal ordered operator therefore has a vacuum expectation value of zero. Although an operator we always have This is particularly useful when defining a quantum mechanical Hamiltonian. If the Hamiltonian of a theory is in normal order then the ground state energy will be zero: Free fieldsWith two free fields φ and χ, where |Ω> is the vacuum state. Each of the two terms on the right hand side typically blows up in the limit as y approaches x but the difference between them has a well-defined limit. This allows us to define :φ(x)χ(x):. Wick's theoremMain article: Wick's theorem Wick's theorem states that:
(with contractions). This theorem provides a simple method for computing vacuum expectation values of operators. This theorem was the reason normal ordering was defined in the first place. References
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