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| Methyl formate | |
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| IUPAC name | Methyl formate |
| Identifiers | |
| CAS number | [107-31-3] |
| SMILES |
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| Properties | |
| Molecular formula | HCOOCH3 |
| Molar mass | 60.05 g/mol |
| Density | 0.98 g/cm³ |
| Melting point |
-100 °C |
| Boiling point |
32 °C |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) Infobox disclaimer and references |
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Methyl formate, also called methyl methanoate, is the methyl ester of formic acid. It is a clear liquid with an ethereal odor, high vapor pressure and low surface tension.
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Production
In the laboratory, methyl formate can be produced by the condensation reaction of methanol and formic acid, as follows:
Industrial methyl formate, however, is usually produced by the combination of methanol and carbon monoxide (carbonylation) in the presence of a strong base, such as sodium methoxide:[1]
This process, practised commercially by BASF amongst other companies gives 96 % selectivity towards methyl formate, although can suffer from catalyst sensitivity to water which can commonly be present in the carbon monoxide feedstock, commonly derived from synthesis gas. Very dry carbon monoxide is therefore an essential requirement.[2]
Uses
Methyl formate is used primarily to manufacture formamide, dimethylformamide, and formic acid. Because of its high vapor pressure, it is used for quick-drying finishes. It is also used as an insecticide and to manufacture certain pharmaceuticals. A historical use of methyl formate which sometimes brings it attention was in refrigeration. Before the introduction of less toxic refrigerants, methyl formate was used as an alternative to sulfur dioxide in domestic refrigerators, such as some models of the famous GE Monitor Top. Owners of methyl formate refrigerators should keep in mind that even though they operate below atmospheric pressure, if evidence of a leak develops, they should take measures to avoid exposure to the ether-smelling liquid and vapor.
References
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This article does not cite any references or sources. (November 2007) Please help improve this article by adding citations to reliable sources. Unverifiable material may be challenged and removed. |
- ^ Process Economics Reports, Review 88-1-1, Process Economics Program, SRI Consulting, California, 1999
- ^ W. Couteau, J. Ramioulle, US Patent US4216339
External links
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