Pb12O19 (monoclinic, dark-brown or black crystals)
The so-called black lead oxide, which is a mixture of PbO and fine-powdered metal Pb and used in the production of lead acid batteries.
The sequence of the thermal transformation between the oxides in air (starting from PbO2) is as follows[1]:
References
^ N.N. Greenwood, A. Earnshaw, "Chemistry of Elements", 2nd edition, Butterworth-Heinemann, 1997.
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