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Homogeneous catalysis
This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Homogeneous_catalysis" .
Homogeneous catalysis is a chemistry term which describes catalysis where the catalyst is in the same phase (ie. solid , liquid and gas ) as the reactants . It is the opposite to heterogeneous catalysis .
Notice that two liquids can be different phases. Therefore, for example, the petrochemical alkylation process features heterogeneous catalysis , although both the catalyst (acid) and reactants (hydrocarbons) are liquids.
The hydrolysis of esters by acid catalysis is an example of this - all reactants and catalyst are dissolved in water:
CH3 CO2 CH3 (aq) + H2 O(l) ↔ CH3 CO2 H(aq) + CH3 OH(aq) - with H+ catalyst.
Contemporary examples of homogeneous catalysis utilizing metal complexes include hydroformylation , Ziegler-Natta polymerization, hydrogen transfer catalysis , hydrogenation , and C-H activation .[1]
References
^ C. Elschenbroich, A. Salzer ”Organometallics : A Concise Introduction” (2nd Ed) (1992) Wiley-VCH: Weinheim. ISBN 3-527-28165-7