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Uses
General uses
Cyanoacrylate is a tenacious adhesive, particularly when used to bond non-porous materials or those that contain minute traces of water. It is also very good at bonding body tissue, and while this can be a bothersome (or even dangerous) side effect during everyday use, it has been exploited for the benefit of suture-less surgery.
Cyanoacrylate glue has a low shearing strength, which has also led to its use as a temporary adhesive in cases where the piece can easily be sheared off at a later time. Common examples include mounting a workpiece to a sacrificial glue block on a lathe and also tightening pins and bolts.
Cyanoacrylates are often used to assemble prototype electronics (see wire wrap), flying model aircraft, and as retention dressings for nuts and bolts. Their effectiveness in bonding metal and general versatility have also made them popular amongst modeling and miniatures hobbyists. They are used to re-harden the boxes and shanks of ballerinas' pointe shoes as well.
Cyanoacrylate glue's ability to resist water has made it popular with marine aquarium hobbists for fragging corals. The cut branches of hard corals such as Acropora can be glued to a piece of live rock or Milliput substrate to allow the new frag to grow out.
Standard cyanoacrylate adhesive is not recommended for use with glass, there are special formulations which are more suitable. However it may be used in conjunction with glass fibre mat or tissue to reinforce joints or to fabricate small parts, reinforcing pins may also be cut from solid fibreglass rod.
When added to baking soda (Sodium bicarbonate), cyanoacrylate glue forms a hard, lightweight filler/adhesive (baking soda is first used to fill a gap then the adhesive is dripped into the baking soda). This works well with porous materials that the glue doesn't work well with alone. This method is sometimes used by aircraft modelers to assemble or repair polystyrene foam parts. Note that the reaction between cyanoacrylate and baking soda is very exothermic (heat producing) and also produces noxious vapors.
One non-adhesive use for cyanoacrylate is as a forensic tool.[1] Fumes from warmed CA can develop latent fingerprints on smooth surfaces like glass, plastic, etc. The invisible fingerprint residues react with the CA fumes and atmospheric moisture to form a white polymer (polycyanoacrylate) on the fingerprint ridges and can then be recorded. The developed fingerprints are, on most surfaces (except on white plastic or similar), visible to the naked eye. Non-visible or poorly visible prints can be furthermore enhanced by applying a luminescent or non-luminescent stain. This technique was shown in the films Beverly Hills Cop II and National Treasure, and frequently features in the television series MacGyver, CSI: Crime Scene Investigation and its spin-offs.
Thin CA glue is also used as a wood finish, particularly among woodturners. Its fast drying time and glossy finish make it ideal for small applications which generally look best when glossy (such as pens), although it is messy and somewhat expensive. A common mistake made by novice users is to use an accelerator, which can cloud and thus ruin the finish.
Some rock climbers use cyanoacrylate to repair damage to the skin on their fingertips.
Properties
In its liquid form, cyanoacrylate consists of monomers of cyanoacrylate molecules. Methyl-2-cyanoacrylate (CH2=C(CN)COOCH3 or C5H5NO2) has a molecular weight equal to 111.1, a flashpoint of 79 °C, and 1.1 times the density of water. Ethyl-2-cyanoacrylate (C6H7NO2) has a molecular weight equal to 125 and a flashpoint of >75°C. To facilitate easy handling, adhesives made with cyanoacrylate are usually formulated so that the glue is more viscous and gel-like.
Generally, cyanoacrylate is an acrylic resin which rapidly polymerises in the presence of water (specifically hydroxide ions), forming long, strong chains, joining the bonded surfaces together. Because the presence of moisture causes the glue to set, exposure to moisture in the air can cause a tube or bottle of glue to become unusable over time. To prevent an opened container of glue from setting before use, it must be stored in an airtight jar or bottle with a package of silica gel.
Another important trait is that cyanoacrylate sets quickly, often in less than a minute. A normal bond reaches full strength in two hours and is waterproof. Accelerators such as toluidine trigger setting in two or three seconds, with some loss of strength.
Acetone, which is commonly found in nail polish remover, is a widely available solvent capable of softening cured cyanoacrylate. Nitromethane is also an excellent solvent. Methylene chloride is the most effective solvent, but is toxic. Gamma-butyrolactone is also effective at removing cured cyanoacrylate, and has low toxicity.
Low temperatures cause cured cyanoacrylate to become brittle. Cyanoacrylate's bonds can be weakened (allowing disassembly) by placing a glued object in a household freezer for several hours. Opened containers of cyanoacrylate glue can also be delayed from prematurely setting by storing the containers in the household refrigerator.
Reaction to Cotton
Applying cyanoacrylate to materials made of cotton or wool (such as cotton swabs, cotton balls, and certain yarns or fabrics) results in a powerful, rapid exothermic reaction. The heat released may cause minor burns, and if enough cyanoacrylate is used, the reaction is capable of setting the cotton product in question on fire, as well as releasing additional irritating vapor in the form of white smoke.[2] Because of this exothermic reaction if spilled on cotton or wool clothing, users should not wear cotton or wool clothing, especially cotton gloves, when applying or handling cyanoacrylates. [3]
Toxicity
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The fumes from CA are a vaporized form of the cyanoacrylate monomer that irritate sensitive membranes in the eyes, nose and throat. They immediately are polymerized by the moisture in the membranes and become inert. About 5% of the population can become sensitized to CA fumes after repeated exposure, resulting in flu-like symptoms.[4] It may also act as a skin irritant and may cause an allergic skin reaction. The ACGIH assign a Threshold Limit Value exposure limit of 200 parts per billion. On rare occasions inhalation may trigger asthma. There can be no singular measurement of toxicity for all cyanoacrylate adhesives as there is a wide variety of adhesives that contain various cyanoacrylate formulations.
However, the National Toxicology Program and the United Kingdom Health and Safety Executive have concluded that the use of ethyl cyanoacrylate is safe and that additional study is unnecessary.[5] 2-octyl cyanoacrylate degrades much more slowly due to its longer organic backbone which slows the degradation of the adhesive enough to remain below the threshold of tissue toxicity. Due to the toxicity issues of ethyl cyanoacrylate, the use of 2-octyl-cyanoacrylate for sutures is preferred.
References
- ^ Eric W. Brown "The Cyanoacrylate Fuming Method"
- ^ Spontaneous Combustion ! - How To Video
- ^ "Material Safety Data Sheet". Retrieved on 2008-06-09.
- ^ Bob Smith Industries - Hobby FAQ
- ^ Methyl Cyanoacrylate and Ethyl Cyanoacrylate
- Fernandez, Tania (Dr) and Bliskovsky, Val (Dr). "Cyanoacrylate Technology: Stay Glued", Pharmbiz.com, 2 January 2003.
- Hayes, Sharon Caskey. "Discovery of Super Glue helped land Coover in National Inventors Hall of Fame", Kingsport Times-News, July 11, 2004.
- Jueneman, F, "Stick it to um", Industrial Research & Development, August 1981, p. 19.
- Perry LC: An evaluation of acute incisional strength with Traumaseal surgical tissue adhesive wound closure. Dimensional Analysis Systems Inc.
- Quinn, J., & Kissack, J., "Tissue Adhesives for Laceration Repair During Sporting Events", Clinical Journal of Sports Medicine, Vol. 4 No. 4, 1994, p. 245.
- Schwade, Nathan D. "Wound Adhesives, 2-Octyl Cyanoacrylate", eMedicine article, 10 April 2002.
- Vinters HV, Galil KA, Lundie MJ, Kaufmann JC: The histotoxicity of cyanoacrylates. A selective review. Neuroradiology 1985; 27(4): 279–91.
External links
- Cyanoacrylate Toxicity
- Cyanoacrylate Adhesive / Super Glue Safety Data Sheets
- Safety in the Home: Super Glue - Queensland Health
Patent
- U.S. Patent 2,768,109 Alcohol-Catalyzed α-Cyanoacrylate Adhesive Compositions, filed June 1954, issued October 1956.
