The autoignition temperature or kindling point of a substance is the lowest temperature at which it will spontaneously ignite in a normal atmosphere without an external source of ignition, such as a flame or spark. This temperature is required to supply the activation energy needed for combustion. The temperature at which a chemical will ignite decreases as the pressure increases or oxygen concentration increases. It is usually applied to a combustible fuel mixture.
Autoignition temperatures of liquid chemicals are typically measured using a 500 mL flask placed in a temperature controlled oven in accordance with the procedure described in ASTM E659 1.
where k = thermal conductivity (W/(m·K)), ρ = density (kg/m³), and c = specific heat capacity (J/(kg·K)) of the material of interest. is the temperature, in kelvins, the material starts at (or the temperature of the bulk material), and q″ is the heat flux (W/m²) incident to the material.
^ E659 – 78 (Reapproved 2000), "Standard Test Method for Autoignition Temperature of Liquid Chemicals", ASTM, 100 Barr Harbor Drive, West Conshohocken, PA 19428-2959