In the Earth's atmosphere, 39Ar is made by cosmic ray activity, primarily with 40Ar. In the subsurface environment, it is also produced through neutron capture by 39K or alpha emission by calcium. The content of 39Ar in natural argon is measured to be of (8.0±0.6)×10−16 g/g, or (1.01±0.08) Bq/kg of natAr [2]. 37Ar is created from the decay of 40Ca as a result of subsurface nuclear explosions. It has a half-life of 35 days.[1] The content of 42Ar in the Earth's atmosphere is lower than 6×10−21 parts per part of natAr [3].
Geologically exceptional samples are known in which the isotopic composition lies outside the reported range. The uncertainty in the atomic mass may exceed the stated value for such specimens.
Values marked # are not purely derived from experimental data, but at least partly from systematic trends. Spins with weak assignment arguments are enclosed in parentheses.
Uncertainties are given in concise form in parentheses after the corresponding last digits. Uncertainty values denote one standard deviation, except isotopic composition and standard atomic mass from IUPAC which use expanded uncertainties.
National Nuclear Data Center, Brookhaven National Laboratory. Information extracted from the NuDat 2.1 database (retrieved Sept. 2005).
David R. Lide (ed.), Norman E. Holden in CRC Handbook of Chemistry and Physics, 85th Edition, online version. CRC Press. Boca Raton, Florida (2005). Section 11, Table of the Isotopes.