History
The Aquatic Species Program launched in 1978. The U.S. research program, funded by the U.S. DoE, was tasked with investigating the use of algae for the production of energy. The program initially focused efforts on the production of hydrogen, however, shifted primary research to studying oil production in 1982. From 1982 through its culmination, the majority of the program research was focused on the production of transportation fuels, notably biodiesel, from algae. In 1995, as part of the over-all efforts to lower budget demands, the DoE decided to end the program. Research stopped in 1996 and staff began compiling their research for publication. In July of 1998, the DoE published the report "A Look Back at the U.S. Department of Energy's Aquatic Species Program: Biodiesel from Algae"13. In 2008, Time Magazine voted Isaac Berzin one of the world's most influential for 2008 for his ability to turn a dream of an oil-free future into a reality through GreenFuel, founded in Boston in 2001. FactorsDry algae factor is the percentage of algae cells in relation with the media where is cultured, e.g. if the dry algae factor is 50%, one would need 2 kg of wet algae (algae in the media) to get 1 kg of algae cells. Lipid factor is the percentage of vegoil in relation with the algae cells needed to get it, i.e. if the algae lipid factor is 40%, one would need 2.5 kg of algae cells to get 1 kg of oil. FuelsThe vegoil algae product can then be harvested and converted into biodiesel; the algae’s carbohydrate content can be fermented into bioethanol and biobutanol.14 BiodieselCurrently most research into efficient algal-oil production is being done in the private sector, but predictions from small scale production experiments bear out that using algae to produce biodiesel may be the only viable method by which to produce enough automotive fuel to replace current world diesel usage.15 Microalgae have much faster growth-rates than terrestrial crops. The per unit area yield of oil from algae is estimated to be from between 5,000 to 20,000 gallons per acre, per year (4.6 to 18.4 l/m2 per year); this is 7 to 30 times greater than the next best crop, Chinese tallow (699 gallons).16 Studies show that algae can produce up to 60% of their biomass in the form of oil. Because the cells grow in aqueous suspension where they have more efficient access to water, CO2 and dissolved nutrients, microalgae are capable of producing large amounts of biomass and usable oil in either high rate algal ponds or photobioreactors. This oil can then be turned into biodiesel which could be sold for use in automobiles. The more efficient this process becomes the larger the profit that is turned by the company. Regional production of microalgae and processing into biofuels will provide economic benefits to rural communities.17 Algae can also grow on marginal lands, such as in desert areas where the groundwater is saline.18 The difficulties in efficient biodiesel production from algae lie in finding an algal strain with a high lipid content and fast growth rate that isn't too difficult to harvest, and a cost-effective cultivation system (i.e., type of photobioreactor) that is best suited to that strain. Another obstacle preventing widespread mass production of algae for biofuel production has been the equipment and structures needed to begin growing algae in large quantities. Diversified Energy Corporation have avoided this problem by taking a different approach, and growing the algae in thin walled polyethylene tubing called Algae Biotape, similar to conventional drip irrigation tubing, which can be incorporated into a normal agricultural environment.19 Open-pond systems for the most part have been given up for the cultivation of algae with high-oil content.20 Many believe that a major flaw of the Aquatic Species Program was the decision to focus their efforts exclusively on open-ponds; this makes the entire effort dependent upon the hardiness of the strain chosen, requiring it to be unnecessarily resilient in order to withstand wide swings in temperature and pH, and competition from invasive algae and bacteria. Open systems using a monoculture are also vulnerable to viral infection. The energy that a high-oil strain invests into the production of oil is energy that is not invested into the production of proteins or carbohydrates, usually resulting in the species being less hardy, or having a slower growth rate. Algal species with a lower oil content, not having to divert their energies away from growth, have an easier time in the harsher conditions of an open system. Some open sewage ponds trial production has been done in Marlborough, New Zealand.21 In a closed system (not exposed to open air) there is not the problem of contamination by other organisms blown in by the air. The problem for a closed system is finding a cheap source of sterile carbon dioxide (CO2). Several experimenters have found the CO2 from a smokestack works well for growing algae.2223 To be economical, some experts think that algae farming for biofuels will have to be done next to power plants, where they can also help soak up the pollution.18 A feasibility study using marine microalgae in a photobioreactor is being done by The International Research Consortium on Continental Margins at the International University Bremen.24 Research into algae for the mass-production of oil is mainly focused on microalgae; organisms capable of photosynthesis that are less than 0.4 mm in diameter, including the diatoms and cyanobacteria; as opposed to macroalgae, e.g. seaweed. However, some research is being done into using seaweeds for biofuels, probably due to the high availability of this resource.25 This preference towards microalgae is due largely to its less complex structure, fast growth rate, and high oil content (for some species). Some commercial interests into large scale algal-cultivation systems are looking to tie in to existing infrastructures, such as coal power plants or sewage treatment facilities. This approach not only provides the raw materials for the system, such as CO2 and nutrients; but it changes those wastes into resources. Aquaflow Bionomic Corporation of New Zealand announced that it has produced its first sample of homegrown bio-diesel fuel with algae sourced from local sewerage ponds. The Department of Environmental Science at Ateneo de Manila University in the Philippines, is working on producing biofuel from algae, using a local species of algae.26 NBB’s Feedstock Development program is addressing production of algae on the horizon to expand available material for biodiesel in a sustainable manner 27. BiobutanolButanol can be made from algae or diatoms using only a solar powered biorefinery. This fuel has an energy density similar to gasoline, and greater than that of either ethanol or methanol. In most gasoline engines, butanol can be used in place of gasoline with no modifications. In several tests, butanol consumption is similar to that of gasoline, and when blended with gasoline, provides better performance and corosion resistance than that of ethanol or E8528. The green waste left over from the algae oil extraction can be used to produce butanol. BiogasolineBiogasoline can be produced from algae. MethaneThrough the use of algaculture grown organisms and cultures, various polymeric materials can be broken down into methane.29 SVOThe algal-oil feedstock that is used to produce biodiesel can also be used for fuel directly as "Straight Vegetable Oil", (SVO). The benefit of using the oil in this manner is that it doesn't require the additional energy needed for transesterification, (processing the oil with an alcohol and a catalyst to produce biodiesel). The drawback is that it does require modifications to a normal diesel engine. Transesterified biodiesel can be run in an unmodified modern diesel engine, provided the engine is designed to use ultra-low sulfur diesel, which, as of 2006, is the new diesel fuel standard in the United States. Hydrocracking to traditional transport fuelsVegetable oil can be used as feedstock for an oil refinery where methods like hydrocracking or hydrogenation can be used to transform the vegetable oil into standard fuels like gasoline and diesel.30 Biofuel from algae by territoryResearch and PromotionThe Ukraine Cabinet plans to produce biofuel of a special type of alga31 . OrganizationsAlgal Biomass Organization (ABO) is formed by Boeing Commercial Airplanes, A2BE Carbon Capture Corporation 32, National Renewable Energy Labs, Institution of Oceanography, Benemann Associates 33, Mont Vista Capital 34 and Montana State University. Global air carriers Air New Zealand, Continental, Virgin Atlantic Airways, and biofuel technology developer UOP LLC, a Honeywell company, will be the first wave of aviation-related members, together with Boeing, to join Algal Biomass Organization.35 Twenty-five airlines went bust or stopped operations in the first six months of 2008 and more could fold as fuel prices soar, aviation industry association IATA has warned.36 Algal jet fuel can be used as alternative: IATA recognizes that aircraft are long lived and will be using kerosene or kerosene-type fuels for many years. It supports research, development & deployment into alternative fuels that produce less GHG emissions over their life cycle and do not compete for land with fuel crops. IATA’s goal is for its members to be using 10% alternative fuels by 2017.2 UniversitiesUS Universities working on Oil from Algae: Algae cultivationAlgae grow rapidly and can have a high percentage of lipids, or oils. They can double their mass several times a day and produce at least 15 times more oil per acre than alternatives such as rapeseed, palms, soybeans, or jatropha. Moreover, algae-growing facilities can be built on coastal land unsuitable for conventional agriculture. The hard part about algae production is growing the algae in a controlled way and harvesting it efficiently. Most companies pursuing algae as a source of biofuels are pumping nutrient-laden water through plastic tubes (called "bioreactors" ) that are exposed to sunlight (and so called photobioreactors or PBR). Running a PBR is more difficult than a open pond, and more costly. WastewaterThere is an option currently being deployed at the Woods Hole Oceanographic Institution and the Harbor Branch Oceanographic Institution and s using wastewater for breeding algae. The wastewater from domestic and industrial sources contain rich organic compounds, which accelerate the growth of algae.14 Also the Department of Biological and Agricultural Engineering of the University of Georgia is exploring microalgal biomass production using industrial wastewater39 . Algaewheel, based in Indianapolis, Indiana, presented a proposal to build a facility in Cedar Lake, Indiana that uses algae to treat municipal wastewater and uses the sludge byproduct to produce biofuel4041. Algal strainsThe following species listed are currently being studied for their suitability as a mass-oil producing crop, across various locations worldwide 42 43 44:
NutrientsNutrients like nitrogen (N), phosphorous (P), and potassium (K), are important for plant growth and are essential parts of fertilizer. Silica and iron may also be considered important marine nutrients as the lack of one can limit the growth of, or productivity in, an area.47 Another possible nutrient source is waste water from the treatment of sewage, agricultural, or flood plain run-off, all currently major pollutants and health risks. However, this waste water cannot feed algae directly and must first be processed by bacteria, through anaerobic digestion. If waste water is not processed before it reaches the algae, it will contaminate the algae in the reactor, and at the very least, kill much of the desired algae strain. In biogas facilities, organic waste is often converted to a mixture of carbon dioxide, methane, and organic fertilizer. Organic fertilizer that comes out of digester is liquid, and nearly suitable for algae growth, but it must first be cleaned and sterilized. One company, Green Star Products, announced their development of a micronutrient formula to increase the growth rate of algae. According to the company, its formula can increase the daily growth rate by 34% and can double the amount of algae produced in one growth cycle.48 See also
References
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