Ammonium persulfate
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Ammonium persulfate
Other names Ammonium Peroxydisulfate
Identifiers
CAS number [7727-54-0]
Properties
Molecular formula (NH4)2S2O8
Molar mass 228.18 g/mol
Appearance white crystals
Melting point

120 °C (393 K) (decomposes)

Solubility in water 80 g/100 ml (25 °C)
Hazards
MSDS http://www.jtbaker.com/msds/englishhtml/a6096.htm
Related compounds
Other cations Sodium persulfate
Potassium persulfate
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

Infobox references

Ammonium persulfate (NH4)2S2O8 is a strong oxidizing agent. It is very soluble in cold water, a large fall of temperature accompanying solution. It is a very strong oxidizing agent and a radical initiator. It is used to etch copper on printed circuit boards as an alternative to ferric chloride solution.[1] It is also used along with tetramethylethylenediamine to catalyze the polymerization of acrylamide in making a polyacrylamide gel.

Ammonium persulfate was prepared by H. Marshall by the method used for the preparation of potassium persulfate — by the electrolysis of a solution of ammonium sulfate and sulfuric acid.[2]

Ammonium persulfate is the main component of Nochromix. On dissolving in sulfuric acid, it is used to clean laboratory glassware as a metal-free alternative to chromic acid baths.[3]

References

  1. ^ "Ammonium Persulphate: Copper Etchant". MG Chemicals.
  2. ^ Hugh Marshall (1891). "LXXIV. Contributions from the Chemical Laboratory of the University of Edinburgh. No. V. The persulphates". J. Chem. Soc., Trans. 59: 771. doi:10.1039/CT8915900771. 
  3. ^ "Nochromix". Sigma-Aldrich. Retrieved on 2008-03-01.


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